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This is the bigger trap. In the United States, the Controlled Substances Analogue Enforcement Act of 1986 makes it illegal to possess documents showing synthetic pathways to Schedule I or II drugs with the intent to manufacture . Simply possessing the PIHKAL PDF is generally protected free speech (you can own Mein Kampf without being a Nazi, and you can own a chemistry text without being a lab chemist). However, possessing the PDF plus a round-bottom flask and a bottle of precursor chemical is often interpreted by prosecutors as "intent."
: For those interested in medicinal chemistry, the Alexander Shulgin Lab Notebooks available via Scribd offer additional raw data from his extensive research. Where to Find the Full Text pihkal pdf